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グルコースのようなアルドヘキソースの5位のヒドロキシルがアルデヒド（位置1）とヘミアセタールを形成する場合、得られる異性体はグルコピラノース.. そのピラノースおよびアルドースの形態としてのD-グルコース位置1に不定中心を有するピラノース構造は、ジアステレオマーおよびジアステレオマーの両方を表す.
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